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How high temperature Water Vapour electrolysis works

Question:
Currently, there are three efficient electrolysis processes ( http://www.geocities.com/TheTropics/Island/4175/tor12.htm ) that can produce H2 from water, i.e. alkaline water electrolysis, high temperature water vapour electrolysis and solid polymer electrolyte water electrolysis. How does Watervapour Electrolysis work?


Answer:
It is basically a solid oxide fuel cell in reverse. The electrolyte is an ionically conducting ceramic oxide, typically yttria doped zirconia. The advantage of working at high temperatures (500 to 1000C) is that the water decomposition starts at a lower voltage so there is potential for greater efficiency. Real units still cost a fortune which is why the underlying theme in the link you give makes me sad. It seems to me they are just looking for an excuse to build dams to destroy more forest, put the country into debt and get rich off the loan repayments.



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